Sapphire (eBook)

Material, Manufacturing, Applications
eBook Download: PDF
2009 | 2009
XX, 480 Seiten
Springer US (Verlag)
978-0-387-85695-7 (ISBN)

Lese- und Medienproben

Sapphire -  Elena R. Dobrovinskaya,  Leonid A. Lytvynov,  Valerian Pishchik
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By the second half of the twentieth century, a new branch of materials science had come into being - crystalline materials research. Its appearance is linked to the emergence of advanced technologies primarily based on single crystals (bulk crystals and films). At the turn of the last century, the impending onset of the 'ceramic era' was forecasted. It was believed that ceramics would play a role comparable to that of the Stone or Bronze Ages in the history of civilization. Naturally, such an assumption was hypothetical, but it showed that ceramic materials had evoked keen interest among researchers. Although sapphire traditionally has been considered a gem, it has developed into a material typical of the 'ceramic era.' Widening the field of sapphire application necessitated essential improvement of its homogeneity and working characteristics and extension of the range of sapphire products, especially those with stipulated properties including a preset structural defect distribution. In the early 1980s, successful attainment of crystals with predetermined char- teristics was attributed to proper choice of the growth method. At present, in view of the fact that the requirements for crystalline products have become more str- gent, such an approach tends to be insufficient. It is clear that one must take into account the physical-chemical processes that take place during the formation of the real crystal structure, i.e., the growth mechanisms and the nature and causes of crystal imperfections.

Elena R. Dobrovinskaya, PhD, is the Chief Scientist at Rubicon Technology, Illinois.  She has over 45 years of experience in Research and Development, and industrial experience in the fields of crystal growth, physical and mechanical properties and defects in single crystals, including the area of sapphire growth and applications (37 years).  Dr. Dobrovinskaya has more than 300 scientific works, 19 patents, and 4 books.
By the second half of the twentieth century, a new branch of materials science had come into being - crystalline materials research. Its appearance is linked to the emergence of advanced technologies primarily based on single crystals (bulk crystals and films). At the turn of the last century, the impending onset of the "e;ceramic era"e; was forecasted. It was believed that ceramics would play a role comparable to that of the Stone or Bronze Ages in the history of civilization. Naturally, such an assumption was hypothetical, but it showed that ceramic materials had evoked keen interest among researchers. Although sapphire traditionally has been considered a gem, it has developed into a material typical of the "e;ceramic era."e; Widening the field of sapphire application necessitated essential improvement of its homogeneity and working characteristics and extension of the range of sapphire products, especially those with stipulated properties including a preset structural defect distribution. In the early 1980s, successful attainment of crystals with predetermined char- teristics was attributed to proper choice of the growth method. At present, in view of the fact that the requirements for crystalline products have become more str- gent, such an approach tends to be insufficient. It is clear that one must take into account the physical-chemical processes that take place during the formation of the real crystal structure, i.e., the growth mechanisms and the nature and causes of crystal imperfections.

Elena R. Dobrovinskaya, PhD, is the Chief Scientist at Rubicon Technology, Illinois.  She has over 45 years of experience in Research and Development, and industrial experience in the fields of crystal growth, physical and mechanical properties and defects in single crystals, including the area of sapphire growth and applications (37 years).  Dr. Dobrovinskaya has more than 300 scientific works, 19 patents, and 4 books.

Preface 5
Contents 7
Symbols 10
Abbreviations 12
Application of Sapphire 13
1.1 Use in Jewelry Industry 16
1.2 Use in Engineering 18
1.3 Use in Optics 25
1.4 Use in Medicine 43
References 54
Properties of Sapphire 67
2.1 Physical Properties 67
2.2 Chemical Properties 140
References 165
Appendix 169
Radiation Effects in Sapphire 189
3.1 Changes on the Surface 191
3.2 Changes in the Bulk 197
References 200
Crystal Growth Methods 201
4.1 Crystallization from the Gaseous (Vapor) Phase 201
4.2 Crystallization from Solution 208
4.3 Growth of Sapphire from the Melt 220
4.4 Solid-Phase Crystal Growth 288
References 295
Appendix 299
The Regularities of Structure Defect Formation at the Crystal Growing 301
5.1 Point Defects 301
5.2 Dislocations 307
5.3 Block Structure of Crystals 328
5.4 Impurity Nonuniformity 334
5.5 “Grain” Structure 341
5.6 Correlation Between Structure Quality of Crystals and Mechanisms of Their Formation 345
5.7 Inclusions in Sapphire 355
References 372
Influence of Chemical–Mechanical Treatment on the Quality of Sapphire Article Working Surfaces and on the Evolution of Surfaces under the Action of Forces 375
6.1 Preliminary Grinding and Lapping 375
6.2 Polishing 377
6.3 Structure of Mechanically Treated Sapphire Surfaces 386
6.4 Control of the Defective Layer during Mechanical Treatment of Sapphire 392
6.5 Prediction of Sapphire Strength Characteristics by Microindentation Methods 402
References 408
The Effect of Thermal Treatment of Crystals on Their Structure Quality and Mechanical Characteristics 411
7.1 Dislocation and Block Structure 412
7.2 Evolution of Impurity Striation 415
7.3 Difference in the Behavior of the Dislocation Ensemble in the Volume and in the Subsurface Layer 418
7.4 Formation of a Dislocation-Free Zone 423
7.5 Anomalies of the Crystal Behavior at High-Temperature Annealing 426
7.6 Influence of the Annealing Medium on the Crystals’ Structure and Their Machinability 429
7.7 Effect of the Annealing Atmosphere on Mechanical Properties 439
7.8 Effect of the Annealing Atmosphere on Optical Properties 439
7.9 Effect of Annealing on Laser Characteristics of Ruby and Sapphire Articles 442
7.10 Stress Relaxation under Annealing 443
7.11 Effect of Annealing on the Crystal Strength 446
7.12 Effect of Annealing on the Optical Inhomogeneity 448
7.13 Effect of Annealing on the Small-Angle Light Scattering in Crystals 452
7.14 Effect of High-Temperature Annealing on the Light Transmittance of Machined Surfaces 454
7.15 Annealing under Loading 455
References 456
Appendix 458
Methods for Obtaining Complex Monolithic Sapphire Units and Large-Size Crystals 459
8.1 Creation of Single-Piece Crystalline Joints 459
8.2 Gluing of Sapphire 460
8.3 Soldering of Sapphire 460
8.4 Welding of Sapphire 462
8.5 Welding by Contact Zone Melting 475
References 478
Conclusion 481
Index 483

Erscheint lt. Verlag 21.4.2009
Reihe/Serie Micro- and Opto-Electronic Materials, Structures, and Systems
Zusatzinfo XX, 480 p. 100 illus.
Verlagsort New York
Sprache englisch
Themenwelt Naturwissenschaften Geowissenschaften Geologie
Naturwissenschaften Physik / Astronomie
Technik Elektrotechnik / Energietechnik
Technik Maschinenbau
Schlagworte Crystal • crystal growth • crystallography • defects • Electronics • Optics • sapphire
ISBN-10 0-387-85695-1 / 0387856951
ISBN-13 978-0-387-85695-7 / 9780387856957
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