Solutions Manual to accompany Organic Chemistry

1. What is organic chemistry? ; 2. Organic structures ; 3. Determining organic structures ; 4. Structure of molecules ; 5. Organic reactions ; 6. Nucleophilic addition to the carbonyl group ; 7. Delocalization and conjugation ; 8. Acidity, basicity, and pKa ; 9. Using organometallic reagents to make C-C bonds ; 10. Nucleophilic substitution at the carbonyl group ; 11. Nucleophilic substitution at C=O with loss of carbonyl oxygen ; 12. Equilibria, rates and mechanisms ; 13. 1H NMR: Proton nuclear magnetic resonance ; 14. Stereochemistry ; 15. Nucleophilic substitution at saturated carbon ; 16. Conformational analysis ; 17. Elimination reactions ; 18. Review of spectroscopic methods ; 19. Electrophilic addition to alkenes ; 20. Formation and reactions of enols and enolates ; 21. Electrophilic aromatic substitution ; 22. Conjugate addition and nucleophilic aromatic substitution ; 23. Chemoselectivity and protecting groups ; 24. Regioselectivity ; 25. Alkylation of enolates ; 26. Reactions of enolates with carbonyl compounds: the aldol and Claisen reactions ; 27. Sulfur, silicon and phosphorus in organic chemistry ; 28. Retrosynthetic analysis ; 29. Aromatic heterocycles 1: structures and reactions ; 30. Aromatic heterocycles 2: synthesis ; 31. Saturated heterocycles and stereoelectronics ; 32. Stereoselectivity in cyclic molecules ; 33. Diastereoselectivity ; 34. Pericyclic reactions 1: cycloadditions ; 35. Pericyclic reactions 2: sigmatropic and electrocyclic reactions ; 36. Participation, rearrangement and fragmentation ; 37. Radical reactions ; 38. Synthesis and reactions of carbenes ; 39. Determining reaction mechanisms ; 40. Organometallic chemistry ; 41. Asymmetric synthesis ; 42. Organic chemistry of life ; 43. Organic chemistry today