Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes
Seiten
2019
Cuvillier Verlag
978-3-7369-7034-2 (ISBN)
Cuvillier Verlag
978-3-7369-7034-2 (ISBN)
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The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
Erscheinungsdatum | 25.06.2019 |
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Verlagsort | Göttingen |
Sprache | englisch |
Maße | 148 x 210 mm |
Gewicht | 190 g |
Themenwelt | Naturwissenschaften ► Chemie |
Schlagworte | Aluminum • Arsinoamide • Boron • crystallographically • Gallium • heterobimetallic • Indium • intermolecular • Magnetic Resonance • metal complexes • metal-to-metal • nitrogen • Phosphinoamide • structural characterization • suitable ligands • synthesis • Thallium • Titanium |
ISBN-10 | 3-7369-7034-X / 373697034X |
ISBN-13 | 978-3-7369-7034-2 / 9783736970342 |
Zustand | Neuware |
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