Advances in Thermoelectric Materials I

Advances in Thermoelectric Materials I (eBook)

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2000 | 1. Auflage
326 Seiten
Elsevier Science (Verlag)
978-0-08-054097-9 (ISBN)
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Since its inception in 1966, the series of numbered volumes known as Semiconductors and Semimetals has distinguished itself through the careful selection of well-known authors, editors, and contributors. The Willardson and Beer series, as it is widely known, has succeeded in producing numerous landmark volumes and chapters. Not only did many of these volumes make an impact at the time of their publication, but they continue to be well-cited years after their original release. Recently, Professor Eicke R. Weber of the University of California at Berkeley joined as a co-editor of the series. Professor Weber, a well-known expert in the field of semiconductor materials, will further contribute to continuing the series' tradition of publishing timely, highly relevant, and long-impacting volumes. Some of the recent volumes, such as Hydrogen in Semiconductors, Imperfections in III/V Materials, Epitaxial Microstructures, High-Speed Heterostructure Devices, Oxygen in Silicon, and others promise that this tradition will be maintained and even expanded.

Reflecting the truly interdisciplinary nature of the field that the series covers, the volumes in Semiconductors and Semimetals have been and will continue to be of great interest to physicists, chemists, materials scientists, and device engineers in modern industry.

Since its inception in 1966, the series of numbered volumes known as Semiconductors and Semimetals has distinguished itself through the careful selection of well-known authors, editors, and contributors. The Willardson and Beer series, as it is widely known, has succeeded in producing numerous landmark volumes and chapters. Not only did many of these volumes make an impact at the time of their publication, but they continue to be well-cited years after their original release. Recently, Professor Eicke R. Weber of the University of California at Berkeley joined as a co-editor of the series. Professor Weber, a well-known expert in the field of semiconductor materials, will further contribute to continuing the series' tradition of publishing timely, highly relevant, and long-impacting volumes. Some of the recent volumes, such as Hydrogen in Semiconductors, Imperfections in III/V Materials, Epitaxial Microstructures, High-Speed Heterostructure Devices, Oxygen in Silicon, and others promise that this tradition will be maintained and even expanded.Reflecting the truly interdisciplinary nature of the field that the series covers, the volumes in Semiconductors and Semimetals have been and will continue to be of great interest to physicists, chemists, materials scientists, and device engineers in modern industry.

Cover 1
Contents 6
Preface 10
List of Contributors 16
Chapter 1. Introduction 18
I. The Thermoelectric Effects 18
II. Semiconductor Thermoelements 26
III. Thermoelectric Materials 30
IV. Limits on the Figure of Merit 35
V. New Developments 37
References 39
Chapter 2. Overview of Measurement and Characterization Techniques for Thermoelectric Materials 42
I. Introduction 42
II. Thermoelectric Materials 44
III. Estimation of the Effect of Errors in Calculating ZT 45
IV. Thermoelectric Measurements 46
V. Summary 64
References 65
Chapter 3. The Role of Solid-State Chemistry in the Discovery of New Thermoelectric Materials 68
I. Introduction 68
II. Necessary Criteria for Thermoelectric Materials 71
III. Solid-State Chemistry as a Tool for Targeted Materials Discovery 72
IV. Thermoelectric Materials Discovery 74
V. New Materials 77
VI. Other Classes of Compounds 109
VII. Conclusions and Outlook 113
References 115
Chapter 4. An Overview of Recent Developments for BiSb Alloys 118
I. Introduction 118
II. Basic Features of the Crystal Structure and the Electronic Structure of Bi1-xSbx Alloys 120
III. Synthesis of Bi„Sb Alloys 130
IV. Transport Properties 137
V. Concluding Remarks 149
References 149
Chapter 5. Skutterudites: Prospective Novel Thermoelectrics 156
I. Introduction 156
II. Structural Aspects and Bonding 158
III. Band Structure 173
IV. Vibrational Properties 184
V. Sample Preparation Aspects 191
VI. Magnetic Properties 197
VII. Transport Properties 213
VIII. Conclusions 263
References 265
Chapter 6. Semiconductor Clathrates: A Phonon Glass Electron Crystal Material with Potential for Thermoelectric Applications 272
I. Introduction 272
II. Synthesis Methods 282
III. Structural Properties 284
IV. Thermal Conductivity 301
V. Electronic Properties 307
VI. Summary and Conclusions 311
References 312
Index 318
Contents of Volumes in This Series 324

Erscheint lt. Verlag 7.11.2000
Mitarbeit Herausgeber (Serie): Terry Tritt
Sprache englisch
Themenwelt Naturwissenschaften Physik / Astronomie
Technik Elektrotechnik / Energietechnik
Technik Maschinenbau
ISBN-10 0-08-054097-X / 008054097X
ISBN-13 978-0-08-054097-9 / 9780080540979
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