Fuel Cell Science (eBook)

Andrzej Wieckowski is Professor of Chemistry at the University of Illinois at Urbana-Champaign. Professor Wieckowski pioneered the development of the method now known as Electrochemical NMR (EC-NMR) that combines metal/surface NMR and electrochemistry for studies of interfaces. Jens K. Nørskov is Professor of Chemical Engineering and Photon Science, Stanford University, and Director of the Center for Interface Science and Catalysis at the SLAC National Accelerator Laboratory. His research interests include the theoretical description of surfaces, catalysis, electrochemistry, materials, nanostructures, and biomolecules.

Foreword vii

Preface xi

Preface to the Wiley Series on Electrocatalysis and Electrochemistry xiii

Contributors xv

1. Hydrogen Reactions on Nanostructured Surfaces 1
Holger Wolfschmidt, Odysseas Paschos, and Ulrich Stimming

2. Comparison of Electrocatalysis and Bioelectrocatalysis of Hydrogen and Oxygen Redox Reactions 71
Marc T. M. Koper and Hendrik A. Heering

3. Design of Palladium-Based Alloy Electrocatalysts for Hydrogen Oxidation Reaction in Fuel Cells 111
Sung Jong Yoo and Yung-Eun Sung

4. Mechanism of an Enhanced Oxygen Reduction Reaction at Platinum-Based Electrocatalysts: Identification and Quantification of Oxygen Species Adsorbed on Electrodes by X-Ray Photoelectron Spectroscopy 147
Mitsuru Wakisaka, Hiroyuki Uchida, and Masahiro Watanabe

5. Biocathodes for Dioxygen Reduction in Biofuel Cells 169
Renata Bilewicz and Marcin Opallo

6. Platinum Monolayer Electrocatalysts: Improving Structure and Activity 215
Kotaro Sasaki, Miomir B. Vukmirovic, Jia X. Wang, and Radoslav R. Adzic

7. The Importance of Enzymes: Benchmarks for Electrocatalysts 237
Fraser A. Armstrong

8. Approach to Microbial Fuel Cells and Their Applications 257
Juan Pablo Busalmen, Abraham Esteve-Nuñez , and Juan Miguel Feliu

9. Half-Cell Investigations of Cathode Catalysts for PEM Fuel Cells: From Model Systems to High-Surface-Area Catalysts 283
Matthias Arenz and Nenad M. Markovic

10. Nanoscale Phenomena in Catalyst Layers for PEM Fuel Cells: From Fundamental Physics to Benign Design 317
Karen Chan, Ata Roudgar, Liya Wang, and Michael Eikerling

11. Fuel Cells with Neat Proton-Conducting Salt Electrolytes 371
Dominic Gervasio

12. Vibrational Spectroscopy for the Characterization of PEM Fuel Cell Membrane Materials 395
Carol Korzeniewski

13. Ab Initio Electrochemical Properties of Electrode Surfaces 415
Ismaila Dabo, Yanli Li, Nicephore Bonnet, and Nicola Marzari

14. Electronic Structure and Reactivity of Transition Metal Complexes 433
Heather J. Kulik and Nicola Marzari

15. Quantitative Description of Electron Transfer Reactions 457
Patrick H.-L. Sit, Agostino Migliore, Michael L. Klein, and Nicola Marzari

16. Understanding Electrocatalysts for Low-Temperature Fuel Cells 489
Peter Ferrin, Manos Mavrikakis, Jan Rossmeisl, and Jens K. Nørskov

17. Operando XAS Techniques: Past, Present, and Future 511
Christina Roth and David E. Ramaker

18. Operando X-Ray Absorption Spectroscopy of Polymer Electrolyte Fuel Cells 545
Eugene S. Smotkin and Carlo U. Segre

19. New Concepts in the Chemistry and Engineering of Low-Temperature Fuel Cells 565
Fikile R. Brushett, Paul. J. A Kenis, and Andrzej Wieckowski

Index 611